If there are applications or commands that you run every single time you start your computer (Email comes to mind) you may want to consider setting things up so that these programs run automatically during the Windows XP startup. This can be done quite easily in XP by creating shortcuts and shuffling them around.
Here's how: Windows XP has a startup folder located at 'C:\ Documents and Settings\ (your user name)\ Start Menu\ Programs\Startup.' Shortcuts placed into this folder will be run automatically when Windows XP starts up.